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Beilstein J. Org. Chem. 2015, 11, 1614–1623, doi:10.3762/bjoc.11.176
Graphical Abstract
Scheme 1: Synthesis of cyclic and polycarbonates.
Figure 1: Bifunctional aluminium–salen complexes, including those studied in this work.
Scheme 2: Synthesis of salen ligands 8a and 8b.
Scheme 3: The preparation of aluminum complexes 1, 2 and 10.
Scheme 4: Possible formation of a dinuclear complex from 1 by treatment with H2O and Et3N.
Figure 2: MALDI–TOF spectrum of poly(hexene carbonate) prepared using catalyst 2. The peak at 565 Daltons cor...
Figure 3: GPC trace of poly(cyclohexene carbonate) prepared using catalyst 2. The chromatogram was obtained i...